Bioactive Wollastonite-Diopside Foams from Preceramic Polymers and Reactive Oxide Fillers

Bioactive Wollastonite-Diopside Foams from Preceramic Polymers and Reactive Oxide Fillers

Wollastonite (CaSiO3) and diopside (CaMgSi2O6) silicate ceramics have been widely investigated as highly bioactive materials, suitable for bone tissue engineering applications. In the present paper, highly porous glass-ceramic foams, with both wollastonite and diopside as crystal phases, were developed from the thermal treatment of silicone polymers filled with CaO and MgO precursors, in the fo...

Ceramic Nanocomposites from Tailor-Made Preceramic Polymers

The present Review addresses current developments related to polymer-derived ceramic nanocomposites (PDC-NCs). Different classes of preceramic polymers are briefly introduced and their conversion into ceramic materials with adjustable phase compositions and microstructures is presented. Emphasis is set on discussing the intimate relationship between the chemistry and structural architecture of ...

Part One Polymers and Fillers

The In Vitro Bioactivity, Degradation, and Cytotoxicity of Polymer-Derived Wollastonite-Diopside Glass-Ceramics

Ca-Mg silicates are receiving a growing interest in the field of bioceramics. In a previous study, wollastonite-diopside (WD) glass-ceramics were successfully prepared by a new processing route, consisting of the heat treatment of a silicone resin embedding reactive oxide particles and a Ca/Mg-rich glass. The in vitro degradation, bioactivity, and cell response of these new WD glass-ceramics, f...

Induced crystallization porosity and properties of sintereds diopside and wollastonite glass-ceramics

diopside (CaO·MgO·2SiO2) and wollastonite (CaO·SiO2) glass-ceramics, forming ∼60% crystal phase and ∼40% albite-like Na2O·Al2O3·6SiO2) residual glass were studied. Two other diopside glass-ceramics with higher Na2O and Al2O3 content were also investigated. The phase formation was estimated by DTA, XRD and pycnometry, while the densification process was evaluated by porosity variations, ilatomet...